118629-76-8

Basic information

• Product Name: 3-Nitro-benzenesulfonic acid (S)-2-hydroxy-propyl ester
• Synonyms: 3-Nitro-benzenesulfonic acid (S)-2-hydroxy-propyl ester
• CAS NO: 118629-76-8
• Molecular Weight: 261.255
• Mol File: 118629-76-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 3-Nitro-benzenesulfonic acid (S)-2-hydroxy-propyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 3-Nitro-benzenesulfonic acid (S)-2-hydroxy-propyl ester(118629-76-8)
• EPA Substance Registry System: 3-Nitro-benzenesulfonic acid (S)-2-hydroxy-propyl ester(118629-76-8)

Safety Data

• Hazardous Substances Data: 118629-76-8(Hazardous Substances Data)

Upstream product

• 121-51-7 3-nitrobenzenesulphonyl chloride 
• 115314-14-2 (R)-glycidyl nosylate 

Relevant articles and documents

Arenesulfonate Derivatives of Homochiral Glycidol: Versatile Chiral Building Blocks for Organic Synthesis

The preparation of a series of crystalline arenesulfonate derivatives of enantiomerically enriched glycidol is described.The enhancement of optical purity by recrystallization was particularly successful for two of these derivatives, glycidyl tosylate and glycidyl 3-nitrobenzenesulfonate, which were obtained in 97 percent ee and 99 percent ee, respectively.Very high regioselectivity was observed in the reactions of these compounds with a variety of nucleophiles, including aryl oxides, Et2AlCN, organometallic reagents, and BH3-NaBH4.The application of this methodology to the synthesis of homochiral β-adrenergic blocking agents and homochiral terminal epoxides is discussed.