1186291-39-3Relevant academic research and scientific papers
Total synthesis of irciniastatin A (psymberin)
Crimmins, Michael T.,Stevens, Jason M.,Schaaf, Gregory M.
supporting information; experimental part, p. 3990 - 3993 (2009/12/03)
The total synthesis of (+)-iriciniastatin A (psymberin) is reported in 19 steps and 6% overall yield. Key reactions include a highly convergent enolsilane-oxocarbenium ion union to generate the C8-C25 fragment and a late-stage coupling of a hemiaminal and
