1186338-52-2Relevant academic research and scientific papers
Reaction of difluorocarbene with propargyl esters and efficient synthesis of difluorocyclopropyl ketones
Hang, Xiao-Chun,Gu, Wei-Peng,Chen, Qing-Yun,Xiao, Ji-Chang
supporting information; experimental part, p. 6320 - 6324 (2009/12/09)
Difluorocarbene generated from FSO2CF2CO2SiMe3 (TFDA) at 120 °C could reacted with terminal alkynes having an ester group at the α position to the triple bond. Difluorocyclopropenes were further converted to difluorocyclopropyl ketones under alkaline condition. Mechanism for the conversion was studied.
