1186497-56-2Relevant academic research and scientific papers
Concise syntheses of the natural products (+)-sylvaticin and (+)-cis-sylvaticin
Donohoe, Timothy J.,Harris, Robert M.,Williams, Oliver,Hargaden, Grainne C.,Burrows, Jeremy,Parker, Jeremy
supporting information; experimental part, p. 12854 - 12861 (2010/01/29)
Two concise syntheses of the natural products cis-sylvaticin and sylvaticin are reported, using oxidative cyclization methodology as the key step. A sequential solvolysis/hydride shift/intramolecular reduction cascade was used to establish the trans stereochemistry of one of the THF rings of sylvaticin.
