1186503-88-7

Basic information

• Product Name: 2-cyclobutyl-6-phenylpyridine
• Synonyms: 2-cyclobutyl-6-phenylpyridine
• CAS NO: 1186503-88-7
• Molecular Formula: C₁₅H₁₅N
• Molecular Weight: 209.2863
• Mol File: 1186503-88-7.mol
• Article Data: 2

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 2-cyclobutyl-6-phenylpyridine(CAS DataBase Reference)
• NIST Chemistry Reference: 2-cyclobutyl-6-phenylpyridine(1186503-88-7)
• EPA Substance Registry System: 2-cyclobutyl-6-phenylpyridine(1186503-88-7)

Safety Data

• Hazardous Substances Data: 1186503-88-7(Hazardous Substances Data)

Upstream product

• 16717-64-9 1-azidostyrene 
• 112650-60-9 1-cyclobutylcyclopropan-1-ol 

Relevant articles and documents

Mn(III)-mediated formal [3+3]-annulation of vinyl azides and cyclopropanols: A divergent synthesis of azaheterocycles

Mn(III)-mediated formal [3+3]-annulation has been developed using readily available vinyl azides and cyclopropanols with a wide range of substituents. Vinyl azides were successfully applied as a three-atom unit including one nitrogen to prepare pyridines and σ-lactams by the reactions with monocyclic cyclopropanols as well as to construct 2-azabicyclo[3.3.1] and 2-azabicyclo[4.3.1] frameworks with bicyclic cyclopropanols, bicyclo[3.1.0]hexan-1-ols, and bicyclo[4.1.0]heptan-1-ols. These reactions were initiated by a radical addition of β-carbonyl radicals, generated by the one-electron oxidation of cyclopropanols with Mn(III), to vinyl azides to give iminyl radicals, which cyclized with the intramolecular carbonyl groups. In addition, application of the present methodology to a synthesis of the quaternary indole alkaloid, melinonine-E, was accomplished.