1186642-22-7Relevant academic research and scientific papers
(EtO)3SiH-promoted palladium-catalyzed isomerization of olefins: Convenient synthesis of internal alkenes from terminal alkenes
Bai, Xing-Feng,Song, Tao,Deng, Wen-Hui,Wei, Yun-Long,Li, Li,Xia, Chun-Gu,Xu, Li-Wen
supporting information, p. 417 - 422 (2014/03/21)
The catalytic activity of an in situ forming palladium catalyst system generated from PdCl2(PPh3)2 and hydrosilane [(EtO)3SiH] was revealed in the one-carbon migration and isomerization of 4,4-biaryl-substituted 1-butenes, in which the (EtO) 3SiH plays a key role in the palladium-catalyzed one-carbon migration and subsequent isomerization of terminal alkenes. This catalytic protocol is applied in the synthesis of a key building block of cassumunin C in high yield and promising selectivity. Georg Thieme Verlag Stuttgart. New York.
Palladium catalyzed isomerization of alkenes: A pronounced influence of an o-phenol hydroxyl group
Fan, Jinmin,Wan, Changfeng,Wang, Qiang,Gao, Linfeng,Zheng, Xiaoqi,Wang, Zhiyong
supporting information; experimental part, p. 3168 - 3172 (2011/02/25)
A novel palladium catalyzed isomerization of alkenes has been found, where an ortho-phenol hydroxyl group has a pronounced influence on the isomerization.
