118713-10-3Relevant academic research and scientific papers
SYNTHESIS OF 1,2-O-CYANOETHYLIDENE DERIVATIVES OF ALKYL GLYCOPYRANURONATES BY OXIDATION OF THE 6-TRITYL ETHERS OF THEIR HEXOSE ANALOGUES
Betaneli, Vitali I.,Ott, Andrej Ya.,Brukhanova, Olga V.,Kochetkov, Nikolay K.
, p. 37 - 50 (1988)
The synthesis of 1,2-O-cyanoethylidene derivatives (CED) of alkyl glycopyranuronates with the D-Glc, D-Gal, and D-Man configurations is described by oxidation of the 3,4-di-O-acetyl-6-O-trityl-CED-hexose analogues with the Jones reagent .The isopropylidenation of hydroxyl-containing triphenylmethyl ethers is demonstrated.
