118715-28-9

Upstream product

• 118715-27-8 5-(tert-butyl-diphenyl-silanyloxy)-pentanoic acid 
• 111-29-5 1 ,5-pentanediol 
• 58479-61-1 tert-butylchlorodiphenylsilane 
• 121671-76-9 5-(tert-butyldiphenylsilyloxy)pentan-1-ol 
• 131216-47-2 5-(tert-butyldiphenylsilyloxy)pentanal 

Downstream Products

• 118722-43-3 5-(tert-Butyl-diphenyl-silanyloxy)-pentanoic acid (2S,3R,4S,5R,6R)-3,4,5-tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yl ester 
• 118715-29-0 5-(tert-Butyl-diphenyl-silanyloxy)-pentanoic acid (2R,3R,4S,5R,6R)-3,4,5-tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yl ester 
• 928658-05-3 C₇₂H₈₈N₂O₇Si₂ 
• 928658-06-4 C₅₈H₇₆N₂O₇Si₂ 
• 928658-07-5 C₅₈H₇₂N₂O₇Si₂ 
• 928658-08-6 C₆₀H₇₆N₂O₅Si₂ 
• 118715-30-3 tert-Butyl-diphenyl-[5-((2S,3R,4S,5R,6R)-3,4,5-tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yloxy)-hex-5-enyloxy]-silane 
• 118715-31-4 tert-Butyl-diphenyl-[5-((2R,3R,4S,5R,6R)-3,4,5-tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yloxy)-hex-5-enyloxy]-silane 
• 118715-34-7 (2R,3R,4S,5R,6S)-3,4,5-Tris-benzyloxy-2-benzyloxymethyl-6-(2-iodomethyl-tetrahydro-pyran-2-yloxy)-tetrahydro-pyran 
• 118715-34-7 (2R,3R,4S,5R,6R)-3,4,5-Tris-benzyloxy-2-benzyloxymethyl-6-(2-iodomethyl-tetrahydro-pyran-2-yloxy)-tetrahydro-pyran 
• 118715-33-6 5-((2S,3R,4S,5R,6R)-3,4,5-Tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yloxy)-hex-5-en-1-ol 
• 118715-32-5 5-((2R,3R,4S,5R,6R)-3,4,5-Tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yloxy)-hex-5-en-1-ol 
• 1356851-38-1 3-(5-((tert-butyldiphenylsilyl)oxy)pentanoyl)benzo[d]oxazol-2(3H)-one 
• 1356851-03-0 (Z)-5-((tert-butyldiphenylsilyl)oxy)-1-(2-oxobenzo[d]oxazol-3(2H)-yl)pent-1-en-1-yl (2-methylallyl) carbonate 

Relevant academic research and scientific papers

Palladium-catalyzed allylic alkylation of carboxylic acid derivatives: N-acyloxazolinones as ester enolate equivalents

Triple A: A general asymmetric allylic alkylation of ester enolate equivalents at the carboxylic acid oxidation state is reported. N-Acylbenzoxazolinone-derived enol carbonates were synthesized and employed in the palladium-catalyzed alkylation reaction. The imide products were readily converted into a series of carboxylic acid derivatives without loss of enantiopurity.

Total synthesis of (+)-nakadomarin A

The total synthesis of (+)-nakadomarin A is described. A three-component cycloaddition of a hydroxylamine, aldehyde, and cyclopropane to form a highly functionalized tetrahydro-1,2-oxazine serves as the foundation for this synthesis. The resulting oxazine