118716-32-8

Basic information

• Product Name: 1-(1-ethoxyethenyl)cyclohexene
• Synonyms: 1-(1-ethoxyethenyl)cyclohexene
• CAS NO: 118716-32-8
• Molecular Weight: 152.236
• Mol File: 118716-32-8.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 1-(1-ethoxyethenyl)cyclohexene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(1-ethoxyethenyl)cyclohexene(118716-32-8)
• EPA Substance Registry System: 1-(1-ethoxyethenyl)cyclohexene(118716-32-8)

Safety Data

• Hazardous Substances Data: 118716-32-8(Hazardous Substances Data)

Upstream product

• 28075-50-5 cyclohex-1-en-1-yl trifluoromethane sulfonate 
• 112713-84-5 trimethyl(1-ethoxylvinyl)tin 
• 109-92-2 ethyl vinyl ether 

Downstream Products

• 932-66-1 1-cyclohexenyl methyl ketone 

Relevant articles and documents

Palladium-Catalyzed Coupling Reactions of (α-Ethoxyvinyl)trimethylstannane with Vinyl and Aryl Triflates

The palladium-catalyzed cross-coupling reaction of vinyl triflates and halides with (α-ethoxyvinyl)trimethylstannane gives high yields of 2-ethoxy 1,3-dienes, which can be hydrolyzed to the corresponding α,β-unsaturated ketones.Aryl triflates undergo an analogous coupling reaction, providing a facile method for replacing the hydroxyl group of a phenol by an acyl group.The use of (α-ethoxyvinyl)trimethylstannane in palladium-catalyzed carbonylative coupling gives rise to vinyl and aryl α-ethoxyvinyl ketones and indirectly to the corresponding α-diketones (which result from their hydrolysis) and glyoxylates (which result from their ozonolysis).