118716-39-5Relevant articles and documents
Regioselective heck couplings of α,β-unsaturated tosylates and mesylates with electron-rich olefins
Hansen, Anders Lindhardt,Skrydstrup, Troels
, p. 5585 - 5587 (2007/10/03)
(Chemical Equation Presented) Highly regioselective Heck couplings of α,β-unsaturated tosylate and mesylate derivatives with N-acyl N-vinylamines and vinyl ethers were achieved. Several 2-alkoxy-1,3-dienes and 2-acylamino-1,3-butadienes were synthesized i
Palladium-Catalyzed Vinylation of Alkyl Vinyl Ethers with Enol Triflates. A Convenient Synthesis of 2-Alkoxy 1,3-Dienes
Andersson, Carl-Magnus,Hallberg, Anders
, p. 1502 - 1505 (2007/10/02)
Reaction of cyclic or acyclic enol triflates with alkyl vinyl ethers in the presence of a palladium catalyst affords 2-alkoxy 1,3-dienes as the major products.The regioselectivity for α-substitution is high (>90percent), and the products can be isolated i