1187457-32-4

Basic information

• Product Name: (1,2-bis(di-tert-butylphosphino)ethane)Ni(MesN=NMes)
• CAS NO: 1187457-32-4
• Molecular Weight: 643.539
• Mol File: 1187457-32-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (1,2-bis(di-tert-butylphosphino)ethane)Ni(MesN=NMes)(CAS DataBase Reference)
• NIST Chemistry Reference: (1,2-bis(di-tert-butylphosphino)ethane)Ni(MesN=NMes)(1187457-32-4)
• EPA Substance Registry System: (1,2-bis(di-tert-butylphosphino)ethane)Ni(MesN=NMes)(1187457-32-4)

Safety Data

• Hazardous Substances Data: 1187457-32-4(Hazardous Substances Data)

Upstream product

• 5692-66-0 2,2',4,4',6,6'-hexamethylazobenzene 

Relevant articles and documents

Group-transfer reactions of nickel-carbene and -nitrene complexes with organoazides and nitrous oxide that form new C=N, C=O, and N=N bonds

(Chemical Equation Presented) 1-Adamantyl- and mesitylazide react with (dtbpe)Ni=CPh2 (1; dtbpe = 1,2-bis(di-tertbutylphosphino) ethane) at ambient temperature to give the ketimines RN=CPh2 (2a, R = Mes; 2b, R = Ad) in high yield. Ki