1187458-54-3Relevant academic research and scientific papers
Stereocontrolled Synthesis of 2-Deoxy- C-glycopyranosyl Arenes Using Glycals and Aromatic Amines
Tang, Shengbiao,Zheng, Qiannan,Xiong, De-Cai,Jiang, Shende,Li, Qin,Ye, Xin-Shan
, p. 3079 - 3082 (2018)
An efficient and stereoselective one-pot, two-step tandem α-arylation of glycals from readily available aryl amines via stable diazonium salts has been developed. Moreover, the stereoselective preparation of the challenging β-C-glycosyl arenes by the anomerization of α-C-glycosides using HBF4 is also described. This protocol has a broad substrate scope and a wide functional-group tolerance. It can be used for the gram-scale preparation of 3-oxo-C-glycosides, which are versatile substrates for the preparation of many biologically important C-glycosides.
Microwave-assisted palladium-catalyzed cross-coupling reactions between pyranoid glycals and aryl bromides. Synthesis of 2′-deoxy C-aryl-β-glycopyranosides
Lei, Ming,Gao, Liang,Yang, Jin-Song
experimental part, p. 5135 - 5138 (2009/12/03)
Under microwave irradiation, perbenzylated pyranoid glycals were coupled with aryl bromides in the presence of 5% mol palladium(II) acetate in dimethylformamide to produce 2′,3′-unsaturated C-aryl-α-glycopyranosides in a rapid and stereospecific manner. T
