118760-75-1Relevant academic research and scientific papers
Effect of Substituent on Reactions Remote from Silicon: Regioselective α-Alkylation of α-Silylallyl Carbanions
Horvath, Raymond F.,Chan, Tak Hang
, p. 317 - 327 (2007/10/02)
α-Silylallyl carbanions having metal-ion complexing substituents on silicon react with alkyl halides to give α-substituted allylsilanes regioselectively.The extent of α-selection depends significantly on the nature of the ligand and solvent.The synthetic utility of these systems is demonstrated by application in the synthesis of α-(E)-bisabolene.
