1187617-95-3Relevant academic research and scientific papers
Alkaloids from alkaloids: total synthesis of (±)-7a-epi-hyacinthacine A1 from Z-protected tropenone via Baeyer-Villiger oxidation
Affolter, Olena,Baro, Angelika,Frey, Wolfgang,Laschat, Sabine
scheme or table, p. 6626 - 6634 (2011/02/26)
Baeyer-Villiger oxidations of several tropane derivatives have been investigated. Whereas tropenones 15a-c underwent exclusive epoxidation to 21a-c, the corresponding 6-oxotropane derivative 28 yielded the desired lactone 29. Baeyer-Villiger oxidation was
