1187666-94-9

Basic information

• Product Name: C₁₀H₁₆N₂
• CAS NO: 1187666-94-9
• Molecular Weight: 164.25
• Mol File: 1187666-94-9.mol

Chemical Properties

• CAS DataBase Reference: C₁₀H₁₆N₂(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₀H₁₆N₂(1187666-94-9)
• EPA Substance Registry System: C₁₀H₁₆N₂(1187666-94-9)

Safety Data

• Hazardous Substances Data: 1187666-94-9(Hazardous Substances Data)

Upstream product

• 95-80-7 4-methylbenzene-1,3-diamine 
• 616-38-6 carbonic acid dimethyl ester 

Relevant articles and documents

Metal organic frameworks as heterogeneous catalysts for the selective N-methylation of aromatic primary amines with dimethyl carbonate

Metal organic frameworks (MOFs) with aluminium, copper and iron as central metal atoms with 1,4-benzenedicarboxylic acid (aluminium) and 1,3,5-benzenetricarboxylic acid (copper and iron) as ligands are selective and active catalysts in promoting the polymethylation of aromatic amines with dimethyl carbonate (DMC). N-methylation prevails over carbamoylation even though they are competing parallel processes. The present N-methylation protocol using DMC enjoys advantages such as convenient reaction conditions, benign, reusable, cost-effective catalyst, avoids the use of additional solvent and uses a safe, green methylating agent that only produces CO2 and methanol as by-products.