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Silicon Compounds with Strong Intramolecular Steric Interactions, 35. - Reactions of 1,2-Dihalodisilanes with Alkali Metal Amides: Formation and Structure of a Tetrahydrodibenzodisilocine
Weidenbruch, Manfred,Pan, Youlin,Peters, Karl,Schnering, Hans Georg von
, p. 885 - 888 (2007/10/02)
Treatment of sterically congested 1,2-dihalodisilanes 1, 2 with alkali metal amides MNHR' (R' = H, Me, Et) gives the corresponding 1,2-diaminodisilanes 3-6.The reaction of 1,2-dichlorotetramesityldisilane (2) with lithium isopropylamide proceeds presumabl
