1188522-06-6Relevant articles and documents
Copper-mediated selective cross-coupling of 1,1-dibromo-1-alkenes and heteronucleophiles: Development of general routes to heterosubstituted alkynes and alkenes
Jouvin, Kevin,Coste, Alexis,Bayle, Alexandre,Legrand, Frederic,Karthikeyan, Ganesan,Tadiparthi, Krishnaji,Evano, Gwilherm
, p. 7933 - 7947 (2013/01/16)
Efficient and general procedures for the cross-coupling of 1,1-dibromoalkenes and N-, O-, and P-nucleophiles are reported. Fine-tuning of the reaction conditions allows for either site-selective, double, or alkynylative cross-coupling, therefore providing
Synthesis of ketene n,n-aeetals by copper-catalyzed double-amidation of 1,1-dibromo-1-alkenes
Coste, Alexis,Couty, Francois,Evano, Gwilherm
supporting information; experimental part, p. 4454 - 4457 (2009/12/24)
An efficient procedure for the preparation of ketene N,N-acetals by copper-catalyzed double amidation of 1,1-dibromo-1-alkenes Is reported. The reaction was found to be general, and ketene aminals could be obtained in good yields when potassium phosphate