118858-80-3Relevant academic research and scientific papers
Kinetics of formation of dihydrogen complexes by protonation of CpRuHL complexes (L = DPPM, DPPE, 2 PPh3) with HBF4·Et2O in THF and the failure to observe dihydrogen complexes in the reactions with other acids
Basallote, Manuel G.,Durán, Joaquín,Fernández-Trujillo, M. Jesús,Má?ez, M. Angeles
, p. 695 - 698 (2000)
The second-order rate constants for the reactions of the title complexes with HBF4 in THF do not correlate with the previously reported pKa's of these complexes. The lack of formation of dihydrogen complexes in their reactions with H
Molecular Hydrogen Complexes: The Effect of Steric Factors on the Protonation of the Monohydrides 5-C5H5)Ru(Ph2P(CH2)nPPh2)H> (n = 1 - 3)
Conroy-Lewis, Fiona M.,Simpson, Stephen J.
, p. 1675 - 1676 (1987)
Protonation of the title complexes leads to either (η2-H2) or trans-dihydride monocations depending on the length of the chain connecting the two phosphine atoms; T1 and JHD measurements are used to support these structure
