118869-05-9Relevant articles and documents
Ethyl acrylate conjugated polystyryl-diphenylphosphine - An extremely efficient catalyst for Henry reaction under solvent-free conditions (SolFC)
Rokhum, Lalthazuala,Bez, Ghanashyam
, p. 300 - 306 (2013)
Over the last few decades, the fast-growing development of polymer supported reagents has led to the synthesis of a variety of reagents on solid support. Some of the major advantages of using such reagents are that they are less hygroscopic, easy to recover, and can be recycled. Here, we have demonstrated that in situ generated ethyl acrylate conjugated polystyryl-diphenylphosphine (PDPP-EA) derived from the reaction of a mixture of polystyryl-diphenylphosphine and ethyl acrylate in a stoichiometric ratio can efficiently catalyze the synthesis of β-nitroalcohols from the reaction of aldehydes and nitroalkanes under solvent-free conditions (SolFC).
Heterogeneous henry reaction of aldehydes: Diastereoselective synthesis of nitroalcohol derivatives over Mg-Al hydrotalcites
Bulbule, Vivek J.,Deshpande, Vishnu H.,Velu, Subramani,Sudalai, Arumugam,Sivasankar,Sathe
, p. 9325 - 9332 (2007/10/03)
Mg-Al Hydrotalcite (HT) has been found to catalyze the reaction between aldehydes and nitroalkanes very efficiently affording threo nitroalkanols in a highly diastereoselective manner. The ratios of threo/erythro isomers are determined from their respecti
