118895-67-3Relevant academic research and scientific papers
Zinc Chloride Catalyzed Rearrangements of 1,2-Dialkynyl-1,2-dihydroxy-3,6-dimethoxy-3,5-cyclohexadienes to Bicyclooctadienones and Bicyclooctadienones
Fernandez, Mario,Chang, Shoumo,Ziller, Joseph,Doedens, Robert J.,Moore, Harold W.
, p. 1379 - 1383 (2007/10/02)
Reported here are unusual rearrangements of 1 and 3 to the bicyclooctadienones 2 and 4.This was accomplished when a carbon tetrachloride solution of respectively 1 and 3 was refluxed for 2 h in the presence of zinc chloride.The structure and stereochemist
