118912-46-2Relevant academic research and scientific papers
Carbonyl group protection method
-
Paragraph 0073; 0074; 0075; 0076, (2017/02/09)
The invention belongs to the technical field of methods for protection of groups in organic chemistry reaction, and particularly discloses a carbonyl group protection method. The response equation is shown in the description, wherein R1 and R2 are alkyl,
Derivatised molecules for mass spectrometry
-
Page 75, (2008/06/13)
Compounds of formula (IIa): are provided where:X is a group capable of being cleaved from the α-carbon atom to form an ion of formula (I')C is a carbon atom bearing a single positive charge or a single negative charge; The invention further provides compounds of formula (IIb): where:X is a counter-ion to C. The compounds of formula (IIa) and (IIb) may form ions of formula (I') by either cleaving the C-X bond between X and the α-carbon atoms in the case of the compounds of formula (IIa) or dissociating X in the case of compounds of formula (IIb).
Design and synthesis of diphenyldiazomethanes possessing stable aminoxyl radicals: Photolytic generation of quartet species and their reaction with C60
Matsuda, Kenji,Ulrich, Gilles,Iwamura, Hiizu
, p. 1581 - 1588 (2007/10/03)
Diphenyldiazomethanes possessing stable tert-butylaminoxyl and Ullman's 'nitronyl nitroxide' radicals were prepared. The corresponding diphenylcarbenes substituted with the free radicals were generated by photolysis of the parent diazomethanes. From EPR f
Novel electron-accepting compound and method for preparing the same
-
, (2008/06/13)
An electron-accepting compound represented by the formula (I): STR1 wherein R represents a hydrogen atom or --B(Mes)2 and Mes represents a mesityl group. A method for preparing an electron-accepting compound represented by the above-described formula (I), which comprises condensing a benzophenone derivative represented by the following formula (II) with malononitride, STR2 wherein R and Mes have the same meanings as defined for the formula (I).
