1189131-04-1Relevant articles and documents
Heterolytic benzene C-H activation by a cyclometalated iridium(III) dihydroxo pyridyl complex: synthesis, hydrogen-deuterium exchange, and density functional study
Meier, Steven K.,Young, Kenneth J. H.,Ess, Daniel H.,Tenn III, William J.,Oxgaard, Jonas,Goddard III, William A.,Periana, Roy A.
, p. 5293 - 5304 (2009)
We report the synthesis of the pincer-cyclometalated (NNC Bu)Ir(III) dihydroxo pyridyl complex 6, which catalyzes hydrogen-deuterium (H/D) exchange between water and benzene in the presence of base (TOF = ~6 x 1O-3 s-1 at