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Valence Isomerizations, 18. - Valence Isomerizations of Persubstituted (CH)10 Systems
Maier, Guenther,Wiegand, Norbert Hermann,Baum, Stefan,Wuellner, Reinhold
, p. 781 - 794 (2007/10/02)
Within the synthesis of persubstituted dihydronaphthalenes, altogether nineteen octamethylbis(methoxycarbonyl)-substituted valence isomers have been isolated, and their structures and mutual relationships clarified.Compared to the unsubstituted parent compounds, there are remarkable differences.The same is true for seven valence-isomeric forms of permethylated (CH)10 hydrocarbons which correspond to diesters and are also presented in this article. - Keywords: Persubstituted (CH)10 systems / Photochemical and thermal isomerizations / Steric crowding / Valence isomerizations
