118921-63-4Relevant academic research and scientific papers
Rhodium- and non-metal-catalyzed approaches for the conversion of isoxazol-5-ones to 2,3-dihydro-6H-1,3-oxazin-6-ones
Jurberg, Igor D.,Davies, Huw M.L.
supporting information, p. 5158 - 5161 (2017/11/06)
Two approaches were developed for the conversion of isoxazol-5-ones to 2,3-dihydro-6H-1,3-oxazin-6-ones. The first involves dirhodium-catalyzed reaction of aryl diazoacetates, leading to rhodium carbene intermediates that undergo insertion into the N-O bo
Reaction of benzene and benzene with Trimethylsilyl Enol Ethers. A New General Method for α-Sulfonyloxylation of Carbonyl Compounds
Moriarty, Robert M.,Penmasta, Raju,Awasthi, Alok K.,Epa, W. Ruwan,Prakash, Indra
, p. 1101 - 1104 (2007/10/02)
Reaction of benzene (1) with trimethylsilyl enol ethers of aromatic ketones 4a-d, alicyclic ketone 7, aliphatic ketone 10, and esters 13a-c in dichloromethane at room temperature gives good yields of α-(tosyloxy)carbonyl compounds 5
