1189350-87-5Relevant academic research and scientific papers
Cross-coupling reaction of organoalane reagents with 2-mercaptobenzo-5-membered heterocycles for efficient synthesis of benzo-5-membered heterocycle sulfides
Luo, Rui-Qiang,Guo, Shao Peng,Xiao, Hong-Liu,Li, Qing-Han
, (2021/12/03)
A highly efficient and simple route for the synthesis of benzo-5-membered heterocycles sulfides has been developed by the cross-coupling reaction of 2-mercaptobenzo-5-membered heterocycles with (hetero)arylaluminum reagents. Various benzo-5-membered heter
Substrate-promoted ligand-free CuI catalyzed S-arylation of 2-mercaptobenzothiazoles with aryl iodides in water
He, Guozhen,Huang, Yuan,Tong, Yao,Zhang, Jie,Zhao, Dan,Zhou, Shuangli,Han, Shiqing
supporting information, p. 5318 - 5321 (2013/09/12)
A green and efficient method has been developed for the cross-coupling of 2-mercaptobenzothiazoles with aryl iodides in water. The reactions proceeded smoothly under ligand-free conditions in the presence of TBAB to give the corresponding products in good yields. The protocol showed good tolerance toward a variety of functional groups. A substrate-promoted mechanism for this catalytic reaction has been proposed.
Copper(I)-catalyzed cascade synthesis of 2-substituted 1,3-benzothiazoles: Direct access to benzothiazolones
Murru, Siva,Mondal, Pravat,Yella, Ramesh,Patel, Bhisma K.
experimental part, p. 5406 - 5413 (2010/02/28)
An efficient cascade process for the preparation of 2-substituted 1,3-benzothiazoles directly from 2-haloaryl isothiocyanates and O or S nucleophiles by a Cu-catalyzed, intramolecular, C-S bond formation has been developed. This cascade method is viable f
Intra- and Intermodular C-S bond formation using a single catalytic system: First direct access to arylthiobenzothiazoles
Murru, Siva,Ghosh, Harisadhan,Sahoo, Santosh K.,Patel, Bhisma K.
supporting information; experimental part, p. 4254 - 4257 (2010/01/06)
We have for the first time developed two llgand-assisted Cu(I)-catalyzed sequential Intra- and intermolecular 5-arylations leading to the direct synthesis of arylthiobenzothlazoles In one pot without an Inert atmosphere. Low catalyst loading, inexpensive
