118947-23-2Relevant academic research and scientific papers
EFFICIENT SYNTHESIS OF CARBOBICYCLIC AND CARBOPOLYCYCLIC COMPOUNDS VIA INTRAMOLECULAR CARBOPALLADATION CATALYSED BY PALLADIUM-PHOSPHINE COMPLEXES
Negishi, Ei-Ichi,Zhang, Yantao,O'Connor, Brian
, p. 2915 - 2918 (1988)
Intramolecular aryl- and alkenylpalladation reactions of cyclic olefins catalyzed by palladium-phosphine complexes, such as Pd(PPh3)4, can produce fused, bridged, and spirofused carbocyclic compounds in high yields.
Synthesis of chiroptical molecular switches by Pd-catalyzed domino reactions
Tietze, Lutz F.,Duefert, Alexander,Lotz, Florian,Soelter, Lars,Oum, Kawon,Lenzer, Thomas,Beck, Tobias,Herbst-Irmer, Regine
supporting information; experimental part, p. 17879 - 17884 (2010/03/30)
New photochromic switches based on helical alkenes can quickly and efficiently be accessed by Pd-catalyzed domino reactions using a modular approach; this allows a wide variability in product formation with the advantages of a convergent synthetic route.
