118967-75-2Relevant academic research and scientific papers
STEREOSELECTIVE ARYLATION OF PYRANOID GLYCALS, USING BROMOMAGNESIUM PHENOLATES : AN ENTRY TO 2,3-UNSATURATED C-α-GLYCOPYRANOSYLARENES
Casiraghi, Giovanni,Cornia, Mara,Rassu, Gloria,Zetta, Lucia,Fava, Giovanna Gasparri,Belicchi, Marisa Ferrari
, p. 243 - 252 (1989)
The arylation of acetylated pyranoid glycals at C-1 by means of bromomagnesium phenolates provides a highly stereoselective entry to 1-C-α-glycopyranosyl-2-hydroxyarenes.
A SIMPLE DIASTEREOSELECTIVE SYNTHESYS OF 2',3'-UNSATURATED ARYL C-GLUCOPYRANOSIDES
Cassiraghi, Giovanni,Cornia, Mara,Rassu, Gloria,Zetta, Lucia,Fava, Giovanna Gasparri,et al.
, p. 3323 - 3326 (2007/10/02)
The regio- and stereoselective arylation at the anomer center of 3,4,5,-tri-O-acetyl-D-glucal (2) by means of bromomagnesium phenolates (1) allows direct preparation of 2',3'-unsaturated 1-C-aryl-α-D-glycosides (3).
