118967-77-4Relevant academic research and scientific papers
Reinvestigation of Phenolic Ferrier Reaction: Selective Synthesis of Aryl O-Δ2-Glycosides
Noshita, Toshiro,Sugiyama, Takeyoshi,Kitazumi, Yoshiharu,Oritani, Takayuki
, p. 2052 - 2055 (2007/10/02)
Reinvestigation of the phenolic Ferrier reaction is described.Ferrier reaction between acetylglycals and phenols in toluene in the presence of a catalytic amount of lewis acid at low temperature gave aryl O-Δ2-glycosides in moderate to good yie
Reaction of 2,3-unsaturated aryl glycosides with Lewis acids: A convenient entry to C-aryl glycosides
Ramesh,Balasubramanian
, p. 3061 - 3064 (2007/10/02)
A facile synthesis of 2',3'-unsaturated-C-aryl glycosides by BF3 · Et2O mediated 'O' to 'C' transformation of 2,3-unsaturated aryl glycosides is reported.
STEREOSELECTIVE ARYLATION OF PYRANOID GLYCALS, USING BROMOMAGNESIUM PHENOLATES : AN ENTRY TO 2,3-UNSATURATED C-α-GLYCOPYRANOSYLARENES
Casiraghi, Giovanni,Cornia, Mara,Rassu, Gloria,Zetta, Lucia,Fava, Giovanna Gasparri,Belicchi, Marisa Ferrari
, p. 243 - 252 (2007/10/02)
The arylation of acetylated pyranoid glycals at C-1 by means of bromomagnesium phenolates provides a highly stereoselective entry to 1-C-α-glycopyranosyl-2-hydroxyarenes.
A SIMPLE DIASTEREOSELECTIVE SYNTHESYS OF 2',3'-UNSATURATED ARYL C-GLUCOPYRANOSIDES
Cassiraghi, Giovanni,Cornia, Mara,Rassu, Gloria,Zetta, Lucia,Fava, Giovanna Gasparri,et al.
, p. 3323 - 3326 (2007/10/02)
The regio- and stereoselective arylation at the anomer center of 3,4,5,-tri-O-acetyl-D-glucal (2) by means of bromomagnesium phenolates (1) allows direct preparation of 2',3'-unsaturated 1-C-aryl-α-D-glycosides (3).
