118968-72-2Relevant academic research and scientific papers
Reaction of halothane with carbonyl compounds in the presence of bases
Ando, Akira,Takahashi, Junko,Nakamura, Yuki,Maruyama, Naoki,Nishihara, Masakazu,Fukushima, Kaori,Moronaga, Jin,Inoue, Mayumi,Sato, Kazuyuki,Omote, Masaaki,Kumadaki, Itsumaro
, p. 283 - 285 (2007/10/03)
The reaction of halothane, 2-bromo-2-chloro-1,1,1-trifluoroethane (1), with aldehydes and ketones in the presence of bases was found to give 1-alkyl- or 1-aryl-2-bromo-2-chloro-3,3, 3-trifluoropropanols (2) or 2-chloro-3,3-difluoro-2-propenols (3) selecti
Facile Conversion of Aldehydes into 1-Substituted 2-Chloro-3,3-difluoro-2-propen-1-ols with 1,1-Dibromo-1-chloro-2,2,2,-trifluoroethane/Magnesium Reagent
Fujita, Makoto,Hiyama, Tamejiro
, p. 3321 - 3322 (2007/10/02)
Aldehydes RCHO are converted in excellent yields into chlorodifluoroallyl alcohols RCH(OH)CCl=CF2 upon treatment with CClBr2CF3 and magnesium in tetrahydrofuran at 0 deg C.
