119-25-5

Basic information

• Product Name: Benzenediazonium, 4-methoxy-2-nitro-, chloride
• CAS NO: 119-25-5
• Molecular Formula: C7H6N3O3.Cl
• Molecular Weight: 215.596
• Mol File: 119-25-5.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Benzenediazonium, 4-methoxy-2-nitro-, chloride(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenediazonium, 4-methoxy-2-nitro-, chloride(119-25-5)
• EPA Substance Registry System: Benzenediazonium, 4-methoxy-2-nitro-, chloride(119-25-5)

Safety Data

• Hazardous Substances Data: 119-25-5(Hazardous Substances Data)

Upstream product

• 96-96-8 4-methoxy-2-nitroaniline 

Downstream Products

• 85355-57-3 1-(2-Bromo-2-chloro-ethyl)-4-methoxy-2-nitro-benzene 
• 6528-34-3 C₁₈H₁₈N₄O₆ 
• 1619995-07-1 12-[5-(4-methoxy-2-nitrophenyl)furan-2-yl]-9,9-dimethyl-7,8,9,10-tetrahydrobenzo[a]acridin-11(12H)-one 
• 1619995-18-4 (E)-N-[5-(4-methoxy-2-nitrophenyl)furan-2-ylmethylidene]naphthalen-2-amine 
• 415943-88-3 5-(4-methoxy-2-nitrophenyl)furan-2-carbaldehyde 
• 110081-47-5 amino-(4-methoxy-2-nitro-phenylhydrazono)-acetic acid ethyl ester 
• 3189-13-7 6-methoxylindole 
• 6178-48-9 6-Carboxy-2,3,4,4'-tetramethoxy-2'-nitro-biphenyl 
• 23501-92-0 C₁₈H₁₉N₃O₇S 
• 111335-06-9 2-[(4-Methoxy-2-nitro-phenyl)-hydrazono]-5-(3-nitro-phenyl)-1,1,3,3-tetraoxo-1λ⁶,3λ⁶-[1,3]dithiane-4,6-dicarboxylic acid dimethyl ester 
• 111335-02-5 5-(4-Dimethylamino-phenyl)-2-[(4-methoxy-2-nitro-phenyl)-hydrazono]-1,1,3,3-tetraoxo-1λ⁶,3λ⁶-[1,3]dithiane-4,6-dicarboxylic acid dimethyl ester 
• 111335-04-7 5-(4-Bromo-phenyl)-2-[(4-methoxy-2-nitro-phenyl)-hydrazono]-1,1,3,3-tetraoxo-1λ⁶,3λ⁶-[1,3]dithiane-4,6-dicarboxylic acid dimethyl ester 
• 111335-08-1 5-(4-Hydroxy-phenyl)-2-[(4-methoxy-2-nitro-phenyl)-hydrazono]-1,1,3,3-tetraoxo-1λ⁶,3λ⁶-[1,3]dithiane-4,6-dicarboxylic acid dimethyl ester 
• 111335-00-3 2-[(4-Methoxy-2-nitro-phenyl)-hydrazono]-5-(4-methoxy-phenyl)-1,1,3,3-tetraoxo-1λ⁶,3λ⁶-[1,3]dithiane-4,6-dicarboxylic acid dimethyl ester 

Relevant articles and documents

METHOD FOR THE PREPARATION OF TRICYCLIC AMINO ALCOHOL DERIVATIVES THROUGH AZIDES

The present invention is directed to processes for the preparation of a tricyclic amino-alcohol derivative useful for treating and preventing diabetes, obesity, hyperlipidemia and the like, which compound is represented by the formula (1): wherein R1 represents a lower alkyl group or a benzyl group; *1 represents an asymmetric carbon atom; R2 represents a hydrogen atom, a halogen atom or a hydroxyl group; and A represents one of the following groups: wherein X represents NH, O or S; R5 represents a hydrogen atom, a hydroxyl group, an amino group or an acetylamino group; and *2 represents an asymmetric carbon atom when R5 is not a hydrogen atom. The processes of the present invention proceed via azide derivatives and are convenient, practical preparing processes with low cost which comprise a small number of steps with good industrial work efficiency.

Synthesis of Substituted Indoles via Meerwein Arylation

A new method for the synthesis of substituted indoles is detailed.Meerwein arylation of 4- and 6-substituted 2-nitrobenzenediazonium chlorides with vinyl acetate or vinyl bromide and subsequent reductive cyclization of the resulting adducts affords the corresponding 6- and 4-substituted (CH3, OCH3, Cl, Br, CF3) indoles.The diazonium bisulfates of weakly basic 2-nitroanilines (4-Cl, 6-Br, 4-CF3) gave higher yields of Meerwein arylation adducts than the corresponding diazonium chlorides.Coupling of 2-nitrobenzenediazonium chloride with 2-acetoxy-1-alkenes followed byreductive cyclization affords 2-alkylindoles.