119005-59-3

Upstream product

• 119005-63-9 methyl onate 
• 119005-72-0 methyl <4,5,7-tri-O-benzyl-2,3-dideoxy-α-D-arabino-2-heptulopyranosid>onate 
• 106-95-6 allyl bromide 
• 55628-54-1 3,4,6-tri-O-benzyl-D-glucal 
• 119068-33-6 phenyl 3,4,6-tri-O-benzyl-2-deoxy-1-sulphonyl-αβ-D-arabino-pyranoside 
• 616-38-6 carbonic acid dimethyl ester 

Downstream Products

• 129778-35-4 (2S,4R,5S,6R)-2-Allyl-4,5-bis-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-carboxylic acid 
• 129778-39-8 3,4,6-tri-O-benzyl-1,2-dideoxy-1β-(prop-2-enyl)-D-arabino-hexopyranose 

Relevant academic research and scientific papers

Diastereoselective Free-Radical Reactions. Part 2. Synthesis of 2-Deoxy-β-C-pyranosides by Diastereoselective Hydrogen-Atom Transfer

C-Glycosides of 2,3-dideoxy-arabino-heptulosonate esters are prepared from the corresponding 2,3-dideoxy-1-phenylsulphonyl derivatives by reductive desulphonylation with lithium naphthalenide and quenching of the so-formed enolate with appropriate alkyl h

Synthesis of 2-deoxy-β-C-pyranosides by diastereoselective hydrogen atom transfer

2-Deoxy-β-C-pyranosides are synthesized by sequential treatment of methyl 3-deoxy-2-phenylsulphonyl-4,5,7-tri-O-benzyl-D-arabino-heptulosonate with lithium naphthalenide and an alkyl halide followed by saponification and reductive decar□ylation. (Chemical