119009-98-2Relevant articles and documents
Use of pyrazolyl ligands for the formation of a bimetallic cobalt-ruthenium complex
Shi, Yifan,Arif, Atta M.,Ernst, Richard D.
, p. 1899 - 1905 (2011)
A straightforward route to Ru(pyz)2(Hpyz)4 (Hpyz = pyrazole) has been developed. This has been found to react readily with a modified Co(pyrazolylborate)Cl complex in the presence of triethylamine as an HCl acceptor to yield a bimetallic cobalt-ruthenium complex, in which the two metals are each six-coordinate, and bridged by three pyrazolyl anions. Both species have been characterized structurally, as has a modified Co(pyrazolylborate)2 complex.