119031-06-0

Basic information

• Product Name: exo(syn 2,3 syn 3,4 dimethyl-2,4 phenyl-4 trimethylsiloxy-3 butanone-1 yl-1)-2 endo methyl-2 bicyclo<2.2.1>heptene-5
• CAS NO: 119031-06-0
• Molecular Weight: 370.607
• Mol File: 119031-06-0.mol

Chemical Properties

• CAS DataBase Reference: exo(syn 2,3 syn 3,4 dimethyl-2,4 phenyl-4 trimethylsiloxy-3 butanone-1 yl-1)-2 endo methyl-2 bicyclo<2.2.1>heptene-5(CAS DataBase Reference)
• NIST Chemistry Reference: exo(syn 2,3 syn 3,4 dimethyl-2,4 phenyl-4 trimethylsiloxy-3 butanone-1 yl-1)-2 endo methyl-2 bicyclo<2.2.1>heptene-5(119031-06-0)
• EPA Substance Registry System: exo(syn 2,3 syn 3,4 dimethyl-2,4 phenyl-4 trimethylsiloxy-3 butanone-1 yl-1)-2 endo methyl-2 bicyclo<2.2.1>heptene-5(119031-06-0)

Safety Data

• Hazardous Substances Data: 119031-06-0(Hazardous Substances Data)

Upstream product

• 119030-96-5 exo-(hydroxy-1 n-propyl)-5 endo-methyl-5 bicyclo<2.2.1>heptene-2 
• 34618-30-9 endo-bicyclo[2.2.1]hept-5-ene-2-methyl-2-carboxaldehyde 

Downstream Products

• 119031-16-2 syn-4,5 syn-5,6 phenyl-6 trimethyl-2,4,6 trimethylsiloxy-5 heptene-1 one-3 

Relevant articles and documents

ALDOLISATION STEREOCONTROLEE PAR UN GROUPE TERMOLABILE. SYNTHESE STEREOSELECTIVE DE COMPOSES POSSEDANT TROIS CARBONES ASYMMETRIQUES CONSECUTIFS.

The bulkiness of thermolabile norbornenyl and oxanorbornenyl groups has been used to induce good to excellent syn diastereoselective aldol condensations between Diels-Alder adducts of α,β-ethylenic ketones and various aldehydes.The aldols thus obtained gi