1190605-24-3Relevant academic research and scientific papers
Syntheses of Structurally and Stereochemically Varied Forms of C7N Aminocyclitol Derivatives from Enzymatically Derived and Homochiral cis-1,2-Dihydrocatechols
Dlugosch, Michael,Ma, Xinghua,Yang, Shuxin,Banwell, Martin G.,Ma, Chenxi,Ward, Jas S.,Carr, Paul
, p. 7225 - 7228 (2018)
The structurally and stereoisomerically varied C7N aminocyclitol derivatives 2-4 have been prepared, using a versatile and flexible range of protocols, from the cis-1,2-dihydrocatechols 5 and 6, homochiral metabolites derived from the whole-cell biotransformation of the corresponding halobenzene. Reaction sequences that enable syntheses of the enantiomeric forms of these derivatives have also been established.
The Synthesis of Certain Phomentrioloxin A Analogues and Their Evaluation as Herbicidal Agents
Taher, Ehab S.,Guest, Prue,Benton, Amanda,Ma, Xinghua,Banwell, Martin G.,Willis, Anthony C.,Seiser, Tobias,Newton, Trevor W.,Hutzler, Johannes
, p. 211 - 233 (2017)
A series of 28 analogues of the phytotoxic geranylcyclohexentriol (-)-phomentrioloxin A (1) has been synthesized through cross-couplings of various enantiomerically pure haloconduritols or certain deoxygenated derivatives with either terminal alkynes or borylated alkenes. Some of these analogues display modest herbicidal activities, and physiological profiling studies suggest that analogue 4 inhibits photosystem II in isolated thylakoids in vitro.
Synthesis and reactivity of a putative biogenetic precursor to tricholomenyns B, C, D and E
Ma, Xinghua,Jury, Jasmine C.,Banwell, Martin G.
scheme or table, p. 2192 - 2194 (2011/05/05)
A chemoenzymatic synthesis of the putative biogenetic precursor, 6, to the epoxy-quinol type natural products, tricholomenyns B, C, D and E (2-5, respectively), has been achieved. However, treatment of compound 6 under a variety of conditions failed to ef
Chemoenzymatic access to versatile epoxyquinol synthons
Pinkerton, David M.,Banwell, Martin G.,Willis, Anthony C.
supporting information; experimental part, p. 4290 - 4293 (2009/12/26)
The enantiomerically pure and readily available metabolites 10-12 have been converted over four simple steps Into the epoxyquinol derivatives 22-24, respectively. Compounds 23 and 24 or their Immediate precursors have been exploited In efficient total syn
Rapid, chemoenzymatic syntheses of the epoxyquinols ()-bromoxone acetate and ()-tricholomenyn A
Pinkerton, David M.,Banwell, Martin G.,Willis, Anthony C.
scheme or table, p. 1639 - 1645 (2010/06/16)
The epoxyquinol derivatives (-)-bromoxone acetate (ent-1) and (-)-tricholomenyn A (2) have been prepared from the cis-1,2-dihydrocatechols 3 and 4, respectively. Compounds 3 and 4 are themselves obtained in enantiomerically pure form through the whole-cel
