1190953-55-9Relevant academic research and scientific papers
A delicate balance between sp2 and sp3 C-H bond activation: A Pt(II) complex with a dual agostic interaction
Crosby, Sarah H.,Clarkson, Guy J.,Rourke, Jonathan P.
, p. 14142 - 14143 (2009)
(Chemical Equation Presented) 2-tert-Butyl-6-(4-fluorophenyl)pyridine reacts with K2PtCl4 via the activation of an sp 2 C-H bond to give a cyclometalated complex that contains a bifurcated agostic interaction. Rearrangemen
Reactions of a platinum(II) agostic complex: Decyclometalation, dicyclometalation, and solvent-switchable formation of a rollover complex
Crosby, Sarah H.,Clarkson, Guy J.,Rourke, Jonathan P.
, p. 3603 - 3609 (2011/09/12)
Good donor ligands react with an sp2 cyclometalated complex of platinum containing an agostic interaction, initially causing displacement of the agostic interaction and decyclometalation. Eventually, these complexes rearrange to give sterically
