1191108-89-0Relevant academic research and scientific papers
Direct catalytic asymmetric aldol reaction of β-keto esters with formaldehyde promoted by a dinuclear Ni2-Schiff base complex
Mouri, Shinsuke,Chen, Zhihua,Matsunaga, Shigeki,Shibasaki, Masakatsu
supporting information; experimental part, p. 5138 - 5140 (2009/12/08)
A homodinuclear Ni2-Schiff base 1 complex (0.1-1 mol%) promoted the direct catalytic asymmetric aldol reaction of β-keto esters with formaldehyde, giving hydroxymethylated adducts in 94-66% ee. The Royal Society of Chemistry 2009.
