119116-57-3Relevant academic research and scientific papers
Simple designs for the construction of complex trans-fused polyether toxin frameworks. A convergent strategy based on hydroxy ketone cyclization of C-linked oxacycles
Alvarez, Eleuterio,Perez, Ricardo,Rico, Milagros,Rodriguez, Rosa M.,Martin, Julio D.
, p. 3003 - 3016 (2007/10/03)
A single, unified convergent strategy for the stereocontrolled synthesis of trans-fused polyethers was developed. It was demonstrated that the epimerization and reductive intramolecular coupling of hydroxy ketones in reactions with silane - Lewis acids (S
A CONVERGENT SYNTHESIS OF THE O-BENZYL DERIVATIVE OF ENANTIO-INEUPATORIOL FROM A CARBOHYDRATE PRECURSOR
Still, Ian W. J.,Banait, Narinder S.,Frazer, Donald V.
, p. 1461 - 1474 (2007/10/02)
The trans-2,3-disubstituted tetrahydropyran 7, obtained in eight steps from methyl α-D-glucoside, and the phosphonium salt 10, obtained from thiophene in six steps, were successfully combined in a Wittig reaction to form 11, the O-benzyl enantiomer of the
