119124-31-1Relevant academic research and scientific papers
Generation of Allylic and Related Organozirconiums Through A Highly Effective Zirconium-β-Alkoxide Elimination Reaction
Ito, Hisanaka,Nakamura, Takanori,Taguchi, Takeo,Hanzawa, Yuji
, p. 4507 - 4518 (2007/10/02)
Reactions and characterization of allylic and related zirconium reaegnts (allenic and γ-alkoxyallylic zirconiums) generated by treatment of allylic and/or propargylic ethers with a zirconocene-butene complex ("Cp2Zr") are described.
Preparation and Reactions of Alkoxy Allylic Zirconium Reagents Derived from Acetals of α,β-Unsaturated Aldehydes: Remarkable Substituent Effects on Regioselectivity
Ito, Hisanaka,Taguchi, Takeo,Hanzawa, Yuji
, p. 7873 - 7876 (2007/10/02)
Alkoxy allylic zirconium reagents, prepared from acetals of α,β-unsaturated aldehydes and "Cp2Zr", react with carbonyl compounds to give 1,2-diols or γ-hydroxy aldehyde derivatives. Key Words: zirconocene; alkoxy allylic zirconium reagent; allylic 1,2-dio
TIN MEDIATED PALLADIUM CATALYZED REGIOCONTROLLED ALKYLATIONS OF VINYL EPOXIDES
Trost, Barry M.,Tenaglia, Alphonse
, p. 2931 - 2934 (2007/10/02)
Cyclic tin ethers react proximal to the oxygen of a vinyl epoxide in a Pd catalyzed etherification as a reflection of templating.
