119139-56-9

Basic information

• Product Name: 3-Oxosapriparaquinone
• Synonyms: 3-Oxosapriparaquinone
• CAS NO: 119139-56-9
• Molecular Formula: C20H24O4
• Molecular Weight: 328.40216
• Mol File: 119139-56-9.mol
• Article Data: 2

Chemical Properties

• Boiling Point: 514.2±50.0 °C(Predicted)
• Appearance: /
• Density: 1.171±0.06 g/cm3(Predicted)
• PKA: 5.11±0.58(Predicted)
• CAS DataBase Reference: 3-Oxosapriparaquinone(CAS DataBase Reference)
• NIST Chemistry Reference: 3-Oxosapriparaquinone(119139-56-9)
• EPA Substance Registry System: 3-Oxosapriparaquinone(119139-56-9)

Safety Data

• Hazardous Substances Data: 119139-56-9(Hazardous Substances Data)

Upstream product

• 170241-31-3 12-benzoyloxy-5,10-friedo-4,5-seco-abieta-5⁽¹⁰⁾,6,8,12-tetraene-3,11,14-trione 
• 181871-22-7 3-hydroxy-5-(3-hydroxy-4-methylpentyl)-2-isopropyl-6-methyl-1,4-naphthoquinone 
• 170241-30-2 12-benzoyloxy-3-hydroxy-5,10-friedo-4,5-seco-abieta-5⁽¹⁰⁾,6,8,12-tetraene-11,14-dione 
• 181871-21-6 1,3,4-triacetoxy-5-(3-acetoxy-4-methylpentyl)-2-isopropyl-6-methylnaphthalene 
• 181871-20-5 5-(3-acetoxy-4-methylpentyl)-2-isopropyl-6-methyl-3,4-naphthoquinone 
• 181871-18-1 5-(3-acetoxy-4-methylpentyl)-2-isopropyl-3-methoxy-6-methylnaphthalene 
• 181871-19-2 5-(3-acetoxy-4-methylpentyl)-2-isopropyl-6-methyl-3-naphthol 
• 181871-16-9 2-isopropyl-3-methoxy-6-methyl-5-(4-methyl-3-oxopentyl)naphthalene 
• 181871-17-0 5-(3-hydroxy-4-methylpentyl)-2-isopropyl-3-methoxy-6-methylnaphthalene 

Relevant articles and documents

A new synthesis of 3-oxosapriparaquinone, a diterpene from Salvia prionitis HANCE (Labiatae)

5,8,11,13-Abietatetraen-3-one (3) and its 12-methoxy derivative (7) were oxidized to the corresponding 3,7-diones, which were rearranged respectively into 2-isopropyl-6-methyl-5-(4-methyl-3-oxopentyl)naphthalene (6) and its 12-methoxy derivative (10) by sodium borohydride reduction and subsequent dehydration with boron trifluoride etherate. Compound 10 was further converted into 3-oxosapriparaquinone (1) via 5-(3-acetoxy-4- methylpentyl)-2-isopropyl-6-methyl-3,4-naphthoquinone (14).