119146-77-9

Basic information

• Product Name: endo-7-methyl-cis-bicyclo<4.1.0>hept-3-ene
• Synonyms: endo-7-methyl-cis-bicyclo<4.1.0>hept-3-ene
• CAS NO: 119146-77-9
• Molecular Weight: 108.183
• Mol File: 119146-77-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: endo-7-methyl-cis-bicyclo<4.1.0>hept-3-ene(CAS DataBase Reference)
• NIST Chemistry Reference: endo-7-methyl-cis-bicyclo<4.1.0>hept-3-ene(119146-77-9)
• EPA Substance Registry System: endo-7-methyl-cis-bicyclo<4.1.0>hept-3-ene(119146-77-9)

Safety Data

• Hazardous Substances Data: 119146-77-9(Hazardous Substances Data)

Upstream product

• 119146-73-5 7-methyl-trans-bicyclo<4.1.0>hept-3-ene 

Relevant articles and documents

Molecules with Twist Bent Bonds. The Synthesis, Properties, and Reactions of trans-Bicyclohept-3-ene and Certain Methylated Derivatives

trans-Bicyclohept-3-ene, 7-methyl-trans-bicyclohept-3-ene, and 7,7-dimethyl-trans-bicyclohept-3-ene have been synthesized.Comparison of their ease of oxidation with the ease of oxidation of the analogous cis-bicyclohept-3-enes has been made.Both the thermal and transition-metal complex promoted rearrangements of the trans-bicyclohept-3-enes have been studied.These systems thermally convert to the cis-bicyclohept-3-enes above 100 deg C and are catalytically rearranged at ambient temperature.Trans to cis isomerization alsooccurs at ambient temperature under photoinduced single electron transfer conditions.