119183-22-1

Usage

Uses

Used in Pharmaceutical Industry:
2,4-Hexadienedioic acid, 3-formyl-, dimethyl ester, (E,Z)is used as a synthetic intermediate for the production of various pharmaceuticals. Its reactivity and unique structure make it a valuable component in the development of new drugs and medicinal compounds.
Used in Polymer and Resin Industry:
2,4-Hexadienedioic acid, 3-formyl-, dimethyl ester, (E,Z)is used as a key ingredient in the synthesis of polymers and resins, contributing to the development of materials with specific properties for various applications, such as coatings, adhesives, and composites.
Used in Fragrance and Flavoring Industry:
2,4-Hexadienedioic acid, 3-formyl-, dimethyl ester, (E,Z)is used as a component in the formulation of fragrances and flavorings, leveraging its unique chemical properties to create distinct scents and tastes in various consumer products.
Used in Organic Chemistry Research:
The (E,Z)isomer of 2,4-Hexadienedioic acid, 3-formyl-, dimethyl ester, (E,Z)- is utilized in organic chemistry research for its potential in various synthetic applications, providing a foundation for the exploration of new chemical reactions and the development of innovative synthetic pathways.

Upstream product

• 103951-59-3 1-(3,4-Dimethoxyphenyl)-2-phenylpropanol 

Relevant academic research and scientific papers

Iron Porphyrin-Catalyzed Oxidation of 1,2-Dimethoxyarenes: A Discussion of the Different Reactions Involved and the Competition between the Formation of Methoxyquinones or Muconic Dimethyl Esters

This paper describes the oxidation of an α,β-diarylpropane lignin dimer model and other dimethoxyarenes by several iron porphyrin-based biomimetic systems.From 1-(3,4-dimethoxyphenyl)-2-phenylpropanol (1), three types of products are identified: the 3,4-dimethoxybenzaldehyde derived from the Cα-Cβ cleavage of the propyl side chain and either quinones or muconic dimethyl esters resulting from oxidations at level of the dimethoxyaryl group.The selectivity of the reaction is discussed with respect to the nature and reactivity of the high-valent iron-oxo species formed upon reaction of the oxidants, H2O2 or magnesium monoperoxyphthalate (MMP), with the iron porphyrins.Fe(TF5PP)Cl-catalyzed oxidation of 1 by H2O2 in an aprotic medium (CH3CN/CH2Cl2), yields a clean "lignin peroxidase-like" reaction with selective formation of the aldehyde.In an aqueous buffered solution, MMP oxidation of para-substituted 1,2-dimethoxyarenes catalyzed by an iron tetrakis(pentafluorophenyl)-β-tetrasulfonatoporphyrin, Fe(TF5PS4P), clearly depends on the electronic properties of the para-substituent.The reaction is selective for para-quinone formation in the case of an electron-releasing group and for muconic dimethyl ester formation in the case of an electron-withdrawing group.