1192-93-4

Upstream product

• 291-64-5 cycloheptane 
• 259173-86-9 2,7-diiodocycloheptanone 

Downstream Products

• 1541-13-5 3-Phenyl-1,3,5-cycloheptatrien 
• 55609-50-2 3-phenyl-(3ar,8ac)-3a,7,8,8a-tetrahydro-cyclohepta[d]isoxazol-4-one 
• 55652-70-5 3-(2,4,6-trimethyl-phenyl)-(3ar,8ac)-3a,7,8,8a-tetrahydro-cyclohepta[d]isoxazol-4-one 
• 16892-50-5 8-Thiabicyclo<3.2.1>octan-3-one 
• 33205-16-2 N-(p-Methoxyphenyl)-8-azabicyclo<3.2.1>octan-3-one 
• 77987-97-4 1,3-Diphenyl-3a,4,5,8a-tetrahydro-1H-cycloheptapyrazol-8-one 
• 63788-76-1 1,3-diphenyl-5,6,7,8-tetrahydro-1H-cycloheptapyrazol-4-one 
• 211447-09-5 Trimethyl-(3-phenyl-cyclohepta-1,6-dienyloxy)-silane 
• 532-24-1 tropinone 
• 63788-78-3 5-(1,3-diphenyl-1H-pyrazol-4-yl)-pentanenitrile 
• 63788-77-2 1,3-diphenyl-3a,4,5,6,7,8a-hexahydro-1H-cycloheptapyrazol-8-one 
• 63788-75-0 1,3-diphenyl-4,5,6,7-tetrahydro-1H-cycloheptapyrazol-8-one 
• 63788-81-8 1,3-diphenyl-3a,4,5,6,7,8a-hexahydro-1H-cycloheptapyrazol-8-one oxime 
• 40698-01-9 8-Thiabicyclo<3.2.1>oct-2-en 

Relevant academic research and scientific papers

Effective oxidation of benzylic and alkane C-H bonds catalyzed by sodium o-iodobenzenesulfonate with Oxone as a terminal oxidant under phase-transfer conditions

Catalytic oxidation of benzylic C-H bonds could be efficiently realized using IBS as a catalyst which was generated in situ from the oxidation of sodium 2-iodobenzenesulfonate (1b) by Oxone in the presence of a phase-transfer catalyst, tetra-n-butylammonium hydrogen sulfate, in anhydrous acetonitrile at 60 °C. Various alkylbenzenes, including toluenes and ethylbenzenes, several oxygen-containing functionalities substituted alkylbenzenes, and a cyclic benzyl ether could be efficiently oxidized. And, the same reagent system of cat. 1b/Oxone/cat. n-Bu4NHSO4 could be applied to the effective oxidation of alkanes as well.

Oxidative Synthesis of α,β-Unsaturated Ketone from α-Iodo Ketone Using Peracid

Oxidation of α-iodo ketone in CH2Cl2 using m-chloro-perbenzoic acid yields α,β-unsaturated ketone by β-H elimination in good yield. This reaction affords a new and convenient synthetic method for α,β-unsaturated ketone from α-iodo ketone.