1192113-36-2Relevant academic research and scientific papers
Indium-mediated catalytic enantioselective allylation of N -benzoylhydrazones using a protonated chiral amine
Kim, Sung Jun,Jang, Doo Ok
supporting information; experimental part, p. 12168 - 12169 (2010/10/03)
A catalytic enantioselective indium-mediated allylation of N-benzoylhydrazones in conjunction with a protonated chiral amine affording enantioenriched homoallylic amines with an extremely high level of enantioselectivity and chemical yield was developed.
Indium(I)-catalyzed asymmetric allylation, crotylation, and αchloroallyalation of hydrazones with rare constitutional and high configurational selectivities
Chakrabarti, Ananya,Konishi, Hideyuki,Yamaguchi, Miyuki,Schneider, Uwe,Kobayashi, Shu
supporting information; experimental part, p. 1838 - 1841 (2010/06/17)
The hydra-zone: The first example of asymmetric In catalysis had been developed. In I combined with a chiral semicorrin ligand (L*) is an effective catalyst for enantioselective allylation, crotylation and α-chloroallylation of hydrazones. In the two latter cases, C-C bond formations proceeded with high selectivity where both reactive aliphatic C-Cl and aromatic O-H bonds were tolerated. Chemical equation representation
The sulfinyl moiety in Lewis base-promoted allylations
Fulton, J. Robin,Kamara, Lamin M.,Morton, Simon C.,Rowlands, Gareth J.
experimental part, p. 9134 - 9141 (2010/01/06)
By employing Senanayake's oxathiazolidine-2-oxide reagent, a collection of sulfinamides was prepared and provided the first examples of sulfinamides promoting the allylation of benzaldehyde and N-benzoylhydrazones with allyltrichlorosilane. The optimum su
