1192138-80-9Relevant academic research and scientific papers
Cyclopropenylcarbinol derivatives as new versatile intermediates in organic synthesis: Application to the formation of enantiomerically pure alkylidenecyclopropane derivatives
Simaan, Samah,Masarwa, Ahmad,Zohar, Elinor,Stanger, Amnon,Bertus, Philippe,Marek, Ilan
supporting information; experimental part, p. 8449 - 8464 (2010/06/15)
The copper-catalyzed carbomagnesiation (or hydrometalation) reaction of chiral cyclopropenylcarbinol derivatives, obtained by means of a kinetic resolution of secondary allylic alcohols, leads to an easy and straightforward preparation of enantiomerically
An efficient, facile, and general stereoselective synthesis of heterosubstituted alkylidenecyclopropanes
Masarwa, Ahmad,Stanger, Amnon,Marek, Ilan
, p. 8039 - 8042 (2008/09/18)
(Chemical Equation Presented) With just a nudge (in the form of silica gel, an acidic ion-exchange resin, or heating at about 40°C), the acetate derivatives of enantiomerically enriched cyclopropenyl alcohols undergo sigmatropic rearrangement to give alky
