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1192306-24-3

ethyl 2-(pivaloyloxy)cyclohex-1-ene-1-carboxylate is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 1192306-24-3 Structure

  • Basic information

    1. Product Name: ethyl 2-(pivaloyloxy)cyclohex-1-ene-1-carboxylate
    2. Synonyms: ethyl 2-(pivaloyloxy)cyclohex-1-ene-1-carboxylate
    3. CAS NO:1192306-24-3
    4. Molecular Formula:
    5. Molecular Weight: 254.326
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 1192306-24-3.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: ethyl 2-(pivaloyloxy)cyclohex-1-ene-1-carboxylate(CAS DataBase Reference)
    10. NIST Chemistry Reference: ethyl 2-(pivaloyloxy)cyclohex-1-ene-1-carboxylate(1192306-24-3)
    11. EPA Substance Registry System: ethyl 2-(pivaloyloxy)cyclohex-1-ene-1-carboxylate(1192306-24-3)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 1192306-24-3(Hazardous Substances Data)

1192306-24-3 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 1192306-24-3 includes 10 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 7 digits, 1,1,9,2,3,0 and 6 respectively; the second part has 2 digits, 2 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 1192306-24:
(9*1)+(8*1)+(7*9)+(6*2)+(5*3)+(4*0)+(3*6)+(2*2)+(1*4)=133
133 % 10 = 3
So 1192306-24-3 is a valid CAS Registry Number.

1192306-24-3Relevant articles and documents

Iron-Catalyzed Cross-Coupling of Alkenyl Acetates

G?rtner, Dominik,Stein, André Luiz,Grupe, Sabine,Arp, Johannes,Von Wangelin, Axel Jacobi

supporting information, p. 10545 - 10549 (2015/09/02)

Stable C-O linkages are generally unreactive in cross-coupling reactions which mostly employ more electrophilic halides or activated esters (triflates, tosylates). Acetates are cheap and easily accessible electrophiles but have not been used in cross-couplings because the strong C-O bond and high propensity to engage in unwanted acetylation and deprotonation. Reported herein is a selective iron-catalyzed cross-coupling of diverse alkenyl acetates, and it operates under mild reaction conditions (0 C, 2 h) with a ligand-free catalyst (1-2 mol%). Iron clad: Acetates are underutilized electrophiles in metal-catalyzed cross-coupling reactions because of the strong alkenyl C-O bond and their propensity to engage in unwanted reactions. Combination of a ligand-free low-valent Fe catalyst with nucleophilic organomagnesium reagents, low temperature, and short reaction times results in highly selective cross-couplings with alkenyl acetates.

Cross-coupling of alkenyl/aryl carboxylates with grignard reagent via Fe-catalyzed C-O bond activation

Li, Bi-Jie,Li, Xu,Wu, Zhen-Hua,Guan, Bing-Tao,Sun, Chang-Liang,Wang, Bi-Qin,Shi, Zhang-Jie

supporting information; experimental part, p. 14656 - 14657 (2010/01/06)

(Chemical Equation Presented) Iron-catalyzed cross-coupling of alkenyl/aryl carboxylates with primary alkyl Grignard reagent was described. This reaction brought a new family of electrophiles to iron catalysis. The combination of an inexpensive carboxylat

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