119239-93-9

Upstream product

• 119146-84-8 (3S,5S)-3,5-Bis-(tert-butyl-dimethyl-silanyloxy)-7-hydroxy-heptanoic acid methyl ester 
• 144320-01-4 exo-3-((tert-butyldimethylsilyl)oxy)-8,9-dioxabicyclo<3.2.2>non-6-ene 
• 119146-82-6 (4R,6S)-Bis-<(tert-butyldimethylsilyl)oxy>-2-cyclohepten-1-one 
• 119146-81-5 Acetic acid (1S,4R,6R)-4-acetoxy-6-hydroxy-cyclohept-2-enyl ester 
• 119182-78-4 6(S)-acetoxy-4-cycloheptene-1(S),3(R)-diol 
• 111795-52-9 (3R,5R,7S)-3,7-dihydroxy-5-((tert-butyldimethylsilyl)oxy)cyclohept-1-ene 
• 134734-53-5 (3S,5S,7R)-3-Acetoxy-5,7-bis-<(tert-butyldimethylsilyl)oxy>cycloheptene 
• 135972-31-5 (4R)-4,7,7-trimethyl-3-exo-(1-naphthyl)bicyclo<2.2.1>heptan-2-exo-yl (3S,5R,6E)-7-phenyl-3,5-dihydroxy-6-heptenoate 
• 135942-74-4 (4R)-4,7,7-trimethyl-3-exo-(1-naphthyl)bicyclo<2.2.1>heptan-2-exo-yl (E,3S)-3-hydroxy-5-oxo-7-phenyl-6-heptenoate 
• 135942-64-2 (4R)-4,7,7-trimethyl-3-exo-(1-naphthyl)bicyclo<2.2.1>heptan-2-exo-yl (E)-7-phenyl-3,5-dioxo-6-heptenoate 
• 26923-50-2 3,4-dehydro-6-(2-phenylethyl)tetrahydropyran-2-one 
• 123185-93-3 (3S,5S)-3,5-Dihydroxy-7-phenyl-heptanoic acid 
• 119146-83-7 (4S,6S)-4,6-Bis-(tert-butyl-dimethyl-silanyloxy)-1-trimethylsilanyloxy-cycloheptene 

Relevant academic research and scientific papers

PLAP-catalysed hydrolysis and optical resolution. Synthesis of 4(S),6(S)-4-hydroxy-6-(2-phenylethyl)tetrahydropyran-2-one: The unnatural mevinolin analog

The oxidation of 3,4-dehydro-6-(2-phenylethyl)tetrahydropyran-2-one (3) by TBHP-DBU proceeds diastereoselectively to furnish a single oxirane (4).Cleavage of the α C-O bond in 4 by NaI in refluxing 2-butanone followed by acylation of the resultant hydroxy