1192541-35-7Relevant academic research and scientific papers
Total syntheses of (+)- and (-)-syringolides 3 and of (+)- and (-)-syributins 1, 2 and 3
Navarro Villalobos, Mauricio,Wood, John L.,Jeong, Susan,Benson, Cristy Lindberg,Zeman, Steven M.,McCarty, Catherine,Weiss, Matthew M.,Salcedo, Analee,Jenkins, Jonathan
, p. 8091 - 8098 (2009)
The first total syntheses of (-)-syringolide 3, (+)-syributin 3 and their unnatural enantiomers (+)-syringolide 3 and (-)-syributin 3 using a common intermediate as starting material are described. In addition, total syntheses of (-)- and (+)-syributins 1
Spirolactone syntheses through a rhodium-catalyzed intramolecular C-H insertion reaction: Model studies towards the synthesis of syringolides
Navarro Villalobos, Mauricio,Wood, John L.
supporting information; experimental part, p. 6450 - 6453 (2011/02/24)
Model studies towards the total synthesis of syringolides using a rhodium-catalyzed intramolecular C-H insertion reaction as the key step are described. A highly stereospecific synthesis of spirolactones is achieved employing this methodology.
