1192622-06-2Relevant academic research and scientific papers
Regioselective metal-catalyzed hydrophosphinylation of alkynes: Synthesis of enantiopure α- or β-substituted vinylphosphane oxides
Duraud, Amelie,Toffano, Martial,Fiaud, Jean-Claude
supporting information; experimental part, p. 4400 - 4403 (2010/01/07)
Palladium was found to catalyze regioselective Markovnikov addition of chiral enantiopure 1r-oxo-2c,5t-diphenyiphospholane (1) to terminal alkynes, whereas rhodium catalysis offers selectively the (E)-anti-Markovnikov adduct, This strategy offers rapid ac
