1192648-76-2Relevant academic research and scientific papers
Excess substrate is a spectator ligand in a rhodium-catalyzed asymmetric [2 + 2 + 2] cycloaddition of alkenyl lsocyanates with tolanes
Oinen, Mark Emil,Yu, Robert T.,Rovis, Tomislav
supporting information; experimental part, p. 4934 - 4937 (2010/01/16)
Excess substrate has been identified as an unintended spectator ligand affecting enantioselectivity In the [2 + 2 + 2] cycloaddition of alkenyl isocyanates with tolanes. Replacement of excess substrate with an exogenous additive affords products with cons
