1192678-82-2

Basic information

• Product Name: (3aS,8aS)-(2,2-DiMethyl-4,4,8,8-tetraphenyl-tetrahydro-[1,3]dioxolo[4,5-e][1,3,2] dioxaphosphepin-6-yl)diMethylaMine
• Synonyms: (3aS,8aS)-(2,2-DiMethyl-4,4,8,8-tetraphenyl-tetrahydro-[1,3]dioxolo[4,5-e][1,3,2] dioxaphosphepin-6-yl)diMethylaMine;(3aR,8aR)-N,N,2,2-tetramethyl-4,4,8,8-tetraphenyl-3a,8a-dihydro-[1,3]dioxolo[4,5-e][1,3,2]dioxaphosphepin-6-amine
• CAS NO: 1192678-82-2
• Molecular Formula: C33H34NO4P
• Molecular Weight: 539.601121
• Mol File: 1192678-82-2.mol
• Article Data: 5

Chemical Properties

• Appearance: /
• CAS DataBase Reference: (3aS,8aS)-(2,2-DiMethyl-4,4,8,8-tetraphenyl-tetrahydro-[1,3]dioxolo[4,5-e][1,3,2] dioxaphosphepin-6-yl)diMethylaMine(CAS DataBase Reference)
• NIST Chemistry Reference: (3aS,8aS)-(2,2-DiMethyl-4,4,8,8-tetraphenyl-tetrahydro-[1,3]dioxolo[4,5-e][1,3,2] dioxaphosphepin-6-yl)diMethylaMine(1192678-82-2)
• EPA Substance Registry System: (3aS,8aS)-(2,2-DiMethyl-4,4,8,8-tetraphenyl-tetrahydro-[1,3]dioxolo[4,5-e][1,3,2] dioxaphosphepin-6-yl)diMethylaMine(1192678-82-2)

Safety Data

• Hazardous Substances Data: 1192678-82-2(Hazardous Substances Data)

Usage

General Description

The chemical "(3aS,8aS)-(2,2-DiMethyl-4,4,8,8-tetraphenyl-tetrahydro-[1,3]dioxolo[4,5-e][1,3,2]dioxaphosphepin-6-yl)diMethylaMine" is a compound with a complex structure that includes a tetrahydro-dioxaphosphepin ring system. It contains two methyl groups and four phenyl groups attached to the ring, as well as a dimethylamine functional group. (3aS,8aS)-(2,2-DiMethyl-4,4,8,8-tetraphenyl-tetrahydro-[1,3]dioxolo[4,5-e][1,3,2] dioxaphosphepin-6-yl)diMethylaMine is likely to have pharmaceutical or chemical applications due to its unique structure, which may contribute to specific interactions with biological or chemical systems. Further research and testing would be needed to fully understand its potential uses and properties.

Upstream product

• 93379-48-7 (R,R)-TADDOL 
• 1608-26-0 Hexamethylphosphorous triamide 
• 124-40-3 dimethyl amine 
• 506-59-2 N,N-dimethylammonium chloride 

Relevant articles and documents

On the role of PIII ligands in the conjugate addition of diorganozinc derivatives to enones

A mechanistic study on the conjugate addition of diethylzinc to cyclohexenone catalyzed by various chiral PIII ligands, provides new insights into its mechanism. Complete in situ conversion of the catalytic amount of Cu(OTf)2 into Cu

Preparation and characterization of new C2- and C 1-symmetric nitrogen, oxygen, phosphorous, and sulfur derivatives and analogs of TADDOL. part II

TADDOL (=α,α,α′,α′-Tetraaryl-1,3- dioxolane-4,5-dimethanol) and the corresponding dichloride are converted to TADDAMINs (=(4S,5S)-2,2,N,N′-tetramethyl-α,α,α′, α′-tetraphenyl-1,3-dioxolan-4,5-dimethanamines) (Scheme 2) and ureas, 12-15, and to TADDOP derivatives with seven-membered O-P-O ester rings (Schemes 3 and 4). Cl/P-Replacement via the Michaelis-Arbuzov reaction (Scheme 7) on mono- and dichlorides, derived from TADDOL, are described. It was not possible to obtain phosphines with the P-atom attached to the benzhydrylic C-atom of the TADDOL skeleton (Schemes 6 and 7). The X-ray crystal structures (Figs. 1 and 2) of ten of the more than 30 new TADDOL derivatives are discussed. Full experimental details are presented. Copyright

Synthesis and application of chiral phosphorus ligands derived from TADDOL for the asymmetric conjugate addition of diethyl zinc to enones

Asymmetric conjugate addition of diethylzinc to cyclohexen-2-one, chalcone, and benzalacetone has been found to occur with 0.5% copper(II) triflate and 1% chiral phosphite. Cyclic phosphites derived from TADDOL gave excellent to moderate enantiomeric exce